A 67-year-old man was also injured following the crash on Lesmahagow Road in Strathaven.
Emergency services were called to the scene on Lesmahagow Road in Strathaven at about 19:00 on Tuesday.
Police Scotland said he was pronounced dead at the scene. A 67-year-old man, who was also in the area, was injured and taken to hospital. A force spokesperson said a 61-year-old woman had been arrested in connection with the incident and inquiries were ongoing.
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